纯PcBN陶瓷材料烧结工艺对内部孔隙的影响Effect of Sintering Process on Porosity of Pure PcBN Ceramic Material
席沛尧,姜士鸿,张鹏,邓福铭
摘要(Abstract):
纯PcBN是新型金属切削刀具材料。通过煮沸称重法得到了高温高压烧结的纯PcBN陶瓷的显孔隙率,使用imageJ2x软件计算纯PcBN陶瓷的分型维数。结果表明,在1700℃、5.8 GPa下,使用15~25μm粒度的cBN粉末烧结得到的纯PcBN孔隙最少;温度降低、压力降低以及降低原料粒度均会导致纯PcBN孔隙增加。在未发生cBN相变的情况下,材料孔隙率的直接因素为原料粒度、塑性变形量和微粉破裂量。
关键词(KeyWords): 纯PcBN;塑性变形;显孔隙率;体积密度;分形维数
基金项目(Foundation): 高等学校博士学科点专项科研基金(20120023110016)
作者(Author): 席沛尧,姜士鸿,张鹏,邓福铭
DOI: 10.16521/j.cnki.issn.1001-9642.2020.05.007
参考文献(References):
- [1]王光祖主编.立方氮化硼制造与应用[M].郑州:郑州大学出版社,2016.
- [2]Luo S Y,Liao Y S,Tsai Y Y.Wear characteristics in turning high hardness alloy steel by ceramic and CBN tools[J].Journal of Materials Processing Technolo gy,1999,88(1-3):114-121.
- [3]Chen W.Cutting forces and surface finish when machining medium hardness steel using CBN tools[J].International Journal of Machine Tools&Manufacture,2000,40(3):455-466.
- [4]Poulachon G,Bandyopadhyay B P,Jawahir I S,et al.Wear behavior of CBN tools while turning various hardened steels[J].Wear,2004,256(3-4):302-310.
- [5]Borkiewicz O,Rakovan J,Cahill C L.Qingsongite,natural cubic boron nitride:The first boron mineral from the Earth's mantle[J].American Mineralogist,2014,99(4):764-772.
- [6]Wentorf R H.Cubic Form of Boron Nitride[J].The Journal of Chemical Physics,1957,26(4):956.
- [7]Qian J,Mukhopadhyay D,Nguyen K D,et al.Sintering of Polycrystalline Boron Nitride Composites for in-situ Synchrotron High Pressure Research[J].International Journal of Refractory Metals and Hard Materials,2015,49:288-291.
- [8]Umer M A,Sub P H,Lee D J,et al.Polycrystalline Cubic Boron Nitride Sintered Compacts Prepared from Nanocrystalline TiN Coated cBN Powder[J].Materials Science and Engineering:A,2012,552:151-156.
- [9]Maweja K,Cornish L A,Can N.Polycrystalline Cubic Boron Nitride Sintered with Ti(C,N)-WA1 Mechanically Alloyed Binders[J].Journal of the European Ceramic Society,2012,32(13):3593-3601.
- [10]Neo K S,Rahman M,Li X P,et al.Performance evaluation of pure CBN tools for machining of steel[J].Journal of Materials Processing Technology,2003,140(1-3):326-331.
- [11]Bushlya V M,Gutnichenko O A,Zhou J M,et al.Tool wear and tool life of PCBN,binderless cBN and wBN-cBN tools in continuous finish hard turning of cold work tool steel[J].Journal of Superhard Ma terials,2014,36(1):49-60.
- [12]Taniguchi T,Akaishi M,Yamaoka S.Sintering of cubic boron nitride without additives at 7.7 GPa and above 2000℃[J].Journal of Materials Research,1999,14(1):162-169.
- [13]Sumiya H,Harano K,Ishida Y.Mechanical properties of nano-polycrystalline cBN synthesized by directconversion sintering under HPHT[J].Diamond and Related Materials,2014,41:14-19.
- [14]Solozhenko V L,Kurakevych O O,Le Godec Y.Creation of Nanostuctures by Extreme Conditions:High-Pressure Synthesis of Ultrahard Nanocrystalline Cubic Boron Nitride[J].Advanced Materials,2012,24(12):1540-1544.
- [15]Tian Y,Xu B,Yu D,et al.Ultrahard Nanotwinned Cubic Boron Nitride[J].Nature,2013,493(7432):385-388.
- [16]李兵,张其龙,马春元.活性炭分形维数与孔隙结构参数的关系,2017[C].
- [17]马骁,谢雪鹏,叶雄伟,等.基于氮气吸附法的钙基地聚合物孔隙结构分形特征[J].材料导报,2019,33(12):1989-1994.